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Anwendungsbeispiele Englisch
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- The Haber–Weiss reaction generates •OH (hydroxyl radicals) from H2O2 (hydrogen peroxide) and superoxide (•O2−) catalyzed by iron ions.
- However, reactive oxygen species generated through the Fenton or Haber-Weiss reactions may enable downstream signaling.
- The aforementioned study by Nojima and coworkers disagrees with this proposal due to three observations: 1) the intermediacy of a cobalt-hydride observed via 1H NMR 2) the propensity of alkenes to undergo autooxidation to the α, β-unsaturated ketones or allylic alcohols when the same reaction is run in the absence of a hydrosilane 3) the predominant mode of decomposition of alkylperoxo-cobalt(III) species to an alkoxy or alkylperoxy radical via the Haber–Weiss mechanism.
- Iron catalyzes the formation of hydroxyl radicals by the Haber–Weiss reaction; such free radicals damage brain cells by peroxidizing lipids in their membranes.
- He left his post two years later to become an assistant to the German chemist Fritz Haber at the Kaiser Wilhelm Institute for Physical Chemistry and Elektrochemistry in Berlin.
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