21 Übersetzungen
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- The compound has been investigated as a reagent for cyclopropanation by the Simmons-Smith reaction, but diiodomethane and chloroiodomethane are preferred.
- In the Simmons–Smith reaction the reactive carbenoid is iodomethylzinc iodide, which is typically formed by a reaction between diiodomethane and a zinc-copper couple.
- The Simmons–Smith reaction is an organic cheletropic reaction involving an organozinc carbenoid that reacts with an alkene (or alkyne) to form a cyclopropane.
- It is an organic compound prepared using the Simmons–Smith reaction, by the action of diiodomethane and a zinc-copper couple on cyclohexene in diethyl ether.
- Iodomethylzinc iodide is the active reagent in the Simmons–Smith reaction.
- Howard Ensign Simmons Jr. (June 17, 1929 – April 26, 1997) was an American chemist with DuPont who discovered the Simmons–Smith reaction.
- These reactions are differentiated in terms of how the carbon is added to form the cyclopropane ring.
- Metal-catalyzed intermolecular carbenoid cyclopropanations are organic reactions that result in the formation of a cyclopropane ring from a metal carbenoid species and an alkene.
© dict.cc English-German dictionary 2024
Enthält Übersetzungen von der TU Chemnitz sowie aus Mr Honey's Business Dictionary (nur Englisch/Deutsch).
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