21 Übersetzungen
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- Acid catalysis is required for this reaction. Often, mercury trifluoroacetate (Hg(OCOCF3)2) is used as a catalyst for the reaction generating an ether with Markovnikov regiochemistry.
- The acidity is strong enough to protonate hydrocarbons and high-silica zeolites are used in acid catalysis processes such as fluid catalytic cracking in petrochemical industry.
- Itaconic acid anhydride is isomerized to citraconic anhydride, which is hydrolyzed and the resulting acid further isomerized under acid-catalysis to give mesaconic acid.
- Although general-acid catalysis for breakdown of the First and Second tetrahedral intermediate may occur by the path shown in the diagram, evidence supporting this mechanism with chymotrypsin has been controverted.
- Active site engineering resulted in loss of the enzyme's ability to form hopanoids, but enabled Brønsted acid catalysis for the stereoselective cyclization of the monoterpenoids geraniol, epoxygeraniol, and citronellal.
- In acid catalysis and base catalysis, a chemical reaction is catalyzed by an acid or a base.
- Traditionally an acidic catalyst in protic solvent was employed with heating, however the reaction has been shown to work in aprotic media in superior yields and sometimes without acid catalysis.
- For example, hexanoyl chloride 1 can be brominated in the alpha-position by NBS using acid catalysis.
- The reaction proceeds by acid catalysis where the double bond in 7 opens to form the carbocation 8.
- Carbonyl ylides can be synthesized by acid catalysis of hydroxy-3-pyrones in the absence of a metal catalyst.
- The reaction can be accelerated by acid catalysis and the equilibrium can be shifted to the right by removal of water.
- In the DuPont route, aniline is converted to diphenyltriazine, which is then converted by acid-catalysis to 4-aminoazobenzene. Hydrogenation of the latter affords PPD.
- Polyamides can also be synthesized from dinitriles using acid catalysis via an application of the Ritter reaction.
- However, evidence for similar general-acid catalysis of the k2 reaction (Tet2) has been controverted; apparently water provides a proton to the amine leaving group.
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Enthält Übersetzungen von der TU Chemnitz sowie aus Mr Honey's Business Dictionary (nur Englisch/Deutsch).
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