NOUN | aziridine | aziridines | |
NOUN article.ind sg | pl
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- Binary ethylenimine (BEI) is a preparation of aziridine.
- It can be viewed as a structural analog of aziridine, with boron replacing the nitrogen atom of aziridine.
- It converts amides to "N"-nitroso derivatives. NOCl converts some cyclic amines to the alkenes. For example, aziridine reacts with NOCl to give ethene, nitrous oxide and hydrogen chloride.
- , an aziridine, is used as a chemotherapeutic agent by virtue of its antitumour activity.
- Alternatively, they can be obtained by oxidation of the corresponding aziridine.
- Iminium ion formation is prohibited in this molecule because the aziridine group and the formyl group are said to be orthogonal.
- A direct approach involves the reaction of aziridine with sulfurous acid.
- Between 400 and 550°C, the cyclic amine, aziridine decomposes to a mixture of "N"-methylmethanimine and ethylideneimine.
- The Blum–Ittah aziridine synthesis, also known as the Blum–Ittah-Shahak aziridine synthesis or simply the Blum aziridine synthesis is a name reaction of organic chemistry, for the generation of aziridines from oxiranes.
- RajanBabu has evaluated asymmetric aziridine openings with high enantioselectivity using yttrium- and lanthanide- salen complexes.
- The De Kimpe aziridine synthesis is suitable for both aldimines and ketamines, particularly those with two alkyl substituents on the α-carbon (Thorpe-Ingold effect).
- A methylene transfer reaction of an imine by an unstabilised sulphonium ylide can give an aziridine system.
- It is a secondary amine and the smallest chiral aziridine (ring containing C2N).
- Divinyl aziridines undergo a similar suite of reactions providing azepines or vinyl pyrrolines depending on the relative configuration of the aziridine starting material.
- It belongs to the class of compounds known as mitomycins, which are characterized by their aziridine ring linked to a 7-amino-6-methyl-cyclohexa[...]pyrrolizine-5,8-dione structure.
- Other names for this are the systematic name 2,3-Aziridinedione or oxalimide.
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Contains translations by TU Chemnitz and Mr Honey's Business Dictionary (German-English only).
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