NOUN | a bromobenzene | bromobenzenes | |
NOUN article.ind sg | pl
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Usage Examples English
- Heating the intermolecular FLP-CO2 compound in bromobenzene at 80 °C under vacuum for 5 hours caused the release of around half of the CO2 and regenerating the two constituent components of the FLP.
- Many simple monosubstituted aromatic compounds bearing the deuterated phenyl (C6D5) group may be purchased commercially, such as aniline, acetophenone, nitrobenzene, bromobenzene, and more.
- Laboratory preparation involves treating bromobenzene with magnesium metal, usually in the form of turnings.
- In experiment one "2-phenylpropionaldehyde" (1, racemic but (R)-enantiomer shown) was reacted with the Grignard reagent of bromobenzene to "1,2-diphenyl-1-propanol" (2) as a mixture of diastereomers, predominantly the threo isomer (see for explanation the Fischer projection).
- ... g. bromobenzene, see Ullmann condensation below). Likewise, this method only gives the best yields for primary halides.
- An example is the reaction of an alkyne-substituted 2-bromobenzene with either sodium sulphide or potassium sulphide to form benzothiophene with an alkyl substitution at position 2.
- Pentaphenylantimony reacts with bromine to make bromobenzene and tetraphenylstibonium bromide.
- In the laboratory it can be prepared by the dehydration of benzamide or benzaldehyde oxime or by the Rosenmund–von Braun reaction using cuprous cyanide or NaCN/DMSO and bromobenzene.
- Gatterman reaction can also be used to convert diazonium salt to chlorobenzene or bromobenzene by using copper powder instead of copper chloride or copper bromide.
- In the mid 1960s, Hurst pursued researches that involved electron swarm measurement, swarm‐beam techniques and swarm drift to determine electron capture cross sections in heavy water, chlorobenzene, bromobenzene, ethylene and ethylene mixtures.
- It results from treating phenylmercury acetate with sodium stannite, by the reaction of mercuric halides with phenylmagnesium bromide, and the reaction of bromobenzene with sodium amalgam.
- His seminal discoveries in this area ranged from tetracyanoethylene oxide, which adds to olefins through its carbon-carbon bond; hexacyanobutadiene, with an oxidation potential near that of bromine; pentacyanocyclopentadiene, an acid as strong as perchloric acid; diiminosuccinonitrile, a remarkable adduct of cyanogen and hydrogen cyanide; and diazodicyanoimidazole, which cleaves to a carbene that forms a bromo ylide with bromobenzene.
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Contains translations by TU Chemnitz and Mr Honey's Business Dictionary (German-English only).
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