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Usage Examples English
- His research focussed on the stereochemistry and conformational analysis of flexible organic molecules, including derivatives of cyclohexane and saturated heterocyclic rings, using nuclear magnetic resonance spectroscopy (NMR) extensively.
- Alliin and related substrates found in nature are chiral at the sulfoxide position (usually having the "S" absolute configuration, and alliin itself was the first natural product found to have both carbon- and sulfur-centered stereochemistry. ...
- "E"–"Z" configuration, or the "E"–"Z" convention, is the IUPAC preferred method of describing the absolute stereochemistry of double bonds in organic chemistry.
- In 1931 the University created a personal Readership in Stereochemistry for him, which he held until his retirement in 1938.
- Glycosyltransferases can be segregated into "retaining" or "inverting" enzymes according to whether the stereochemistry of the donor's anomeric bond is retained (α→α) or inverted (α→β) during the transfer.
- ... invert stereochemistry) with respect to the carbon center, the same rules apply.
- Unlike most 1,3-dipolar cycloaddition reactions, in which the stereochemistry of the dipole is lost or non-existent, azomethine ylides are able to retain their stereochemistry.
- Importance: standard advanced text for organic stereochemistry.
- Stereochemistry spans the entire spectrum of organic, inorganic, biological, physical and especially supramolecular chemistry.
- Its absolute stereochemistry, however, was not characterized until 2009.
- The stereochemistry and mechanism of enolate formation have gained much interest in the chemistry community.
- Partial to complete racemization of stereochemistry in solutions are a result of SN1 mechanisms.
- Halohydrins that possess a trans stereochemistry have been demonstrated to form epoxides and transposed products in the presence of Fétizon's reagent.
- The stereochemistry of momilactone B shown here is based on the biosynthesis references.
- When the stereochemistry of the first carbon matches the stereochemistry of the last stereogenic center the sugar is the α-anomer when they are opposite the sugar is the β-anomer.
- The two rings are fused in a "cis" configuration—this meso compound formally has (1"R",4"S") absolute stereochemistry.
- Professor Klyne was writing a book on organic stereochemistry for Chapman & Hall and John’s expertise and attention to detail made him the ideal co-author.
- Stabilized or "soft" nucleophiles invert the stereochemistry of the [...] -allyl complex.
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Contains translations by TU Chemnitz and Mr Honey's Business Dictionary (German-English only).
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